Nope,, never been bit on the toe.
The only snake to ever bite me was a black snake. I had rescured it from a barking dog,, and the snake was focused solely on the dog as I picked it up.
Well,, as it sat coiled up in my open palmed hands,, it decided that the dog was no longer a threat,, and decided to take out it's frustrations on the biggest thing it could find,, my nose. I saw it about to strike,, and was in the process of just gently tossing it back on the grass, when it barely got the tip of my nose. The 3 of us standing there got a good chuckle,, as I didn't have hardly any marks. (But my nose is big enough to make it an easy target!)
Tell that 8 yr old youngun' that it's not necessarily brave,, it's just that I understand the critters,, and I was NOT harming or threatening it in any way.