Believe your refering to increasing the throat diameter of the cylinder to "match " the barrel diameter. Not sure about the .41 , but many of the older .45 Colts had throat diameters much smaller ( and larger ) than bore size , hence a bullet was squeezed or actually resized going through the throat ...then enters the barrel and wobbles down the length of the barrel. This causes accuracy problems. Also may be a major factor in leading, as the hot gas blows by the bullet and melts it against the barrel. My .45 Bisley has throats at .451.5 , as it came from the factory. I believe the newer Rugers have better tolerances , probably due to better machining processes. I'm sure someone here can help you with your .41 , as far as what it should or shouldn't be. I know just enuf to get me in trouble :D Thats the basic idea of throat reaming ... you may or maynot need it.
regards , brushunter