So a few thoughts...
Leading in a bore can and WILL indeed cause sticky cases, even in revolvers. So will copper fouling, but copper fouling builds a lot more slowly than leading, and it's a lot higher lubricity than lead, so it takes a LOT more rounds to start building problems with copper fouling. BUT, yes, indeed, leading in the bore can cause excessive pressures, especially when you're shooting higher velocity rounds like .44mag or .454C. Been there, done that. Had cases sticking in a .44mag SBH that traditionally always drops the rounds without the use of the ejector rod. Noticed a few flattened primers, remembered I'd been burning through some hardcast as I was shooting that revolver for Cowboy Action Long Range side matches. I scrubbed the bore, no more issues. It does happen. Happened on a regular basis in my Marlin 1894's, 1895's, and H&R Buffalo Classic shooting lead in high volume for Cowboy Action Shooting, just never thought of it in non-closed breech weapons until my SBH started acting up.
Granted, you didn't mention shooting a TON of lead yourself, and I can't imagine Ruger or Talo put THAT many rounds down your Toklat (my bore didn't show any lead nor copper when I got my Toklat), to have produced a constricted bore for you... So on to my next point...
Beyond that, sticky cases happen to Ruger SRH's in .454C and .480R. It just happens. I've noticed it worse with .454C than I did with the .480, but it does happen. Polishing your chamber won't fix it, but can help, in general. As has been mentioned, the proprietary alloy that Ruger uses in the SRH 454 and 480 cylinders has a high elasticity. It's incredibly strong, but comparably, it's quite "stretchy". The case obturates to fill the chamber, the chamber obturates slightly, the case stretches with it, but the brass doesn't spring back, the cylinder does, boom, sticky case. Not surprisingly, the heavier loads under heavier bullets tend to produce more stuck cases. I have had to use a poly mallet to eject stuck cases in my 7.5" SRH more than a few times - that poly mallet found its way into my range bag because I needed it to remove cases from my .480R 7.5" and Alaskan SRH's.
I've also had some sticky cases with the heavier factory loads, but at the price of factory fodder, I rarely shoot it.
I've had luck in my SRH's with using a bit of case lube when shooting at the range. About 1 in 5 loadings keeps the cases falling out. Naturally, don't add too much otherwise you'll get deformations. I just stick an RCBS lube pad on the loading bench, set 6 rounds on it, roll them over once and back, and load it up. Ain't an ideal system, but it works well enough.
I lube the living daylights out of any lead bullets I'm shooting before reloading. Seems to help reduce lead fouling, at least in my head
Unfortunately, you're unlikely to notice flattened primers in the 454C as an early indicator of excessive pressure. The 454C uses small rifle primers specifically for the stronger primer cup. Presents a challenge in terms of "light" firing pin strikes in the 454C SRH's (doesn't happen in the .44mag's 'cuz they use pistol primers!), as well as a bit of a "numb" primer when it comes to pressure signs. Especially in loadings that might use magnum SR primers with a thicker still cup. I've seen flattening of the headstamp impressions in 454C without giving what I would have called a "flattened primer". It's almost scary when you lose such an important safety check, definitely unnerved me when I started shooting 454's ~10yrs ago.
I'd highly recommend that you slug your throats. Ruger is notorious for running tight throats. I haven't slugged my own Toklat yet, but I'm planning on going ahead with a ream job on it anyway (also chamfering the chambers and reaming the forcing cone). I've never bought a Ruger Revolver (out of over 50 of them) that had proper chamber throats for a full cylinder.
Also, if you intend to continue shooting lead, even hardcast bullets, you'll be doing yourself a favor to ream your forcing cone to 11degrees. At the pressures the 454C generates, frankly lead just isn't hard enough, so it'll lead in a 454C SRH faster than most other weapons. I hate lead in general, but in my Alaskan 454's I see leading after a box or two that looks like my 45colt or 44mag Cowboy action revolvers after hundreds of rounds. The lengthened forcing cone helps reduce that fouling a lot. I've never noticed that it hurts accuracy with jacketed bullets thereafter either, so really it's a benefit with no downside.
I know that's not much help, but I'd really say I'm not surprised to hear you had sticky cases. I also won't be surprised to hear if you get light pin strikes and misfires. If you DO start seeing misfires, Bowen Classic Arms sells 30 and 40lb mainsprings (you WILL want a lighter trigger return spring in that case) and they also offer extended firing pins - but be warned, it's a $100-150 job for a $15 part to replace the firing pin in an SRH. No idea what BCA charges, had one done locally and did another myself (gotta admit, I wouldn't do it again myself). If you're good with calipers, you can also hone the tip of the hammer to maximize your firing pin protrusion, but be careful that you don't produce a hammer "pinch" on the transfer bar. The hammer stand off needs to be a few thousandths taller than the transfer bar such that it can release when the trigger is released (becomes more of an issue when you stick that lighter trigger return spring and that heavy 40lb hammer spring in your SRH!!). You'll also need to verify that the drilled "dimple" in the hammer face is still deep enough such that the hammer doesn't contact the firing pin when the transfer bar isn't raised, again, a few thou gap.
If you do think you have a problem batch of ammo, I'd recommend you go through the process of slugging your chamber throats, then invest in a small powder scale and pull the bullets, weigh the charges, and check the diameters on the bullets. Another easy answer would be to try a different lot number of the same brand, but since you seem pretty adverse to spending any more money on their stuff, that's probably out of the question.