Every time you work brass, it gets a little bit more brittle. It's called work hardening, and has to do with the crystalline structure of metals (yes, they have a crystalline structure
). Think about what happens when you take a paper clip and bend it back and forth a few times. The less you work the brass, the longer it will last. With new brass, or brass that has been full length sized, the entire cartridge is just smaller than the chamber to ensure that the round will chamber in a firearm with a chamber that is machined to the very small end of the SAAMI specs. Since most chambers fall in the middle or even toward the top end, it leaves a lot of room between the chamber and the brass. When you fire the round, the pressure expands the brass outward until stopped by the chamber, and the brass then springs back just a tiny amount, allowing it to be extracted.
When you full-length size the brass, the die returns it to that small size again, working all that brass. Every time you fire and full length size, it works the brass on the entire cartridge, including reworking the shoulder of the cartridge.
In comparison, a neck sizer only works the small neck of the cartridge, and leaves the rest of the brass alone. Because the tolerances on the neck area of the chamber are generally held tighter, the neck doesn't expand as much. It just needs to be worked a tiny bit to hold tension on the bullet. Because you're only working a small amount of the brass, and you're working it a relatively small amount, it doesn't work harden as much or as quickly.
I hope that makes sense.