Clovishound said:
Word on the street is that Alliant has a 100+ year old sample of the first run of Unique that they periodically take some out, dry and test it. Still good after all these years. Hey, you can sing that to a Paul Simon song.
I haven't seen anything official on that, but have heard it from some knowledgeable people.
Hi,
Hercules used to have a picture of that powder covered by water in its glass container in their loading guides. If memory serves, Alliant kept the picture for a short while, too. Somewhere I think I may still have a copy of it, but it would take forever to dig that deep.

A fellow over at the S&W Forum references it, though his link to the original article doesn't work for me. His quote:
"Unique was first manufactured in about 1898 and was one of the first powders Du Pont turned over to Hercules. A jar of Unique powder sits on the shelf at the Alliant Powder plant in Radford, Virginia. The powder in the jar was made in 1899 and still performs to original specifications. 'Unique is the oldest and most versatile powder on the market,' Quesenberry says."
http://smith-wessonforum.com/reloading/99292-shelf-life-unique-powder.html
As for age, I have about 3 lbs left out of a 15 lb keg of Unique I got long ago. I don't know the exact year, but judging by the size of the keg (they dropped the largest size to 12 lbs in the early '80s, then to 8 lbs sometime later), and the price of $62.50, I'm gonna guess mid to late-70s, so it's 40 years old or more. Performs like new. I finished its companion 15 lb keg of Green Dot just a couple of years ago--it still worked, too, though not quite as consistently as the Unique.
Rick C